Saturday, August 1, 2020

Virus and bacteria inactivation by CO2 bubbles in solution

https://www.nature.com/articles/s41545-018-0027-5

Virus and bacteria inactivation by CO2 bubbles in solution

Abstract

The availability of clean water is a major problem facing the world. In particular, the cost and destruction caused by viruses in water remains an unresolved challenge and poses a major limitation on the use of recycled water. Here, we develop an environmentally friendly technology for sterilising water. The technology bubbles heated un-pressurised carbon dioxide or exhaust gases through wastewater in a bubble column, effectively destroying both bacteria and viruses. The process is extremely cost effective, with no concerning by-products, and has already been successfully scaled-up industrially.

Introduction

Wastewater usually contains human enteric viruses like hepatitis and rotavirus and bacteria like Escherichia coli. If this water is to be reused it has to be disinfected. Collivignarelli et al.1 found that ultraviolet (UV) irradiation and chemical treatments using chlorine, chlorine dioxide, peracetic acid or ozone were the most used technologies for wastewater disinfection. However, all these water disinfection technologies have limitations. For example, chlorine and chlorine dioxide react with organic compounds and form reactive chlorinated organic compounds that are hazardous to humans. In addition, chlorine needs at least 30 min contact time and is not able to eliminate Cryptosporidium. Chlorine dioxide has high management costs and is very unstable. Other disinfection methods such as ozone and UV irradiation are complex to operate and maintain. Rotavirus can be resistant to UV treatments and its efficiency is affected by the dissolved organic and inorganics in the wastewater, as well as its colour and turbidity.2 Paracetic acid increases chemical oxygen demand (COD) and biochemical oxygen demand (BOD) due to the formation of acetic acid.1 Therefore, a major challenge exists to develop new, energy-efficient technologies to address these problems.
Here we report on one such candidate technology for sterilisation that seems to do the job. It uses atmospheric pressure bubbles of CO2 in a new device (ABCD). If this process successfully inactivates MS2 virus (ATCC15597-B1) and E. coli C-3000 (ATCC15597), that are surrogates for enteric pathogens, then this technology will be able to inactivate real waterborne viruses and bacteria for water reuse without the need for (high energy) boiling.
In preceding work3,4 we conducted different experiments where the bubble diameter of 1–3 mm was measured using high speed cameras. An earlier variant we called the hot bubble column evaporator (HBCE) process.5,6,7 It used hot air bubbles of 1–3 mm diameter and was operated in the temperature range of 150–250 °C. The bubbles transferred heat to surrounding water and thermally inactivated dispersed viruses and bacterial cells. At the same time, low, steady-state solution temperatures in the range of 42–55 °C were maintained.8 An instantaneous transient hot surface layer must also form around the rising, initially hot, air bubbles. The inactivation process clearly involves collisions of bacteria or viruses with the hot air bubbles5,6 and the surrounding heated layers.7 Other gases (air, N2, O2 and Argon) achieved similar inactivation results, at 200 °C inlet gas temperatures for viruses and at 150 °C for bacteria.9 However, CO2 gas, at the same inlet gas temperature, is far superior with much higher inactivation rates at lower temperatures than with other gases.9 Hence, we here embark on a more thorough study of the effects of CO2 bubbling on viral and bacterial inactivation in pure sodium chloride solutions, using the HBCE device at atmospheric pressure with the acronym ABCD.
Many waste disposal industries like landfills, bio-gas plants and coal power plants emit large amounts of CO2. Hence, the potential use of CO2 bubbles in water treatment processes to sterilise water at atmospheric pressure offers an attractive new technology at the very least. Earlier we showed9 too that the heat generated in exhaust combustion gases that contain CO2 can also be used to increase the performance of this new sterilisation treatment. That we will also take further.
The process is very different to others that involve CO2. Thus, many authors10 have shown that pressurised CO2 in a range of 5 to 1000 atm can achieve viral and bacterial inactivation.
High-pressure carbon dioxide has been proposed as a cold pasteurisation alternative for more than 25 years.11 The new ABCD reactor, described here, achieves equivalent or better results but without the need for pressurisation, i.e., at just 1 atm. The process has been patented by the University of New South Wales as Australian Patent Application No. 2017904797.

Biodegradable foam


We have had biodegradable foam peanuts now for some time.

But I am looking at using foam as a lightweight , low cost (hopefully) building material for everything from robots to houses.

The problem is the full life cycle.  How does one dispose of massive amounts of plastic or foam from whole building contrustructed from it.  Cement, and concretes are broken up and reused as filler dumped in to landfill.

The wood is recycled or landfill, today wood is too expensive to just scrap from old buildings.

Metals are easily recycled.

What happens with Fiberglass, and other materials like gypsum board. this is all landfilled, and at least there is nothing toxic leaching out.

I want something I can made model airplane wings from, skyscraper facades from .


https://en.wikipedia.org/wiki/Foam_peanut

Search Results

Featured snippet from the web

Biodegradable packing peanuts are made from natural, nontoxic sources, such as wheat and corn starch. They dissolve in water and can be thrown into compost piles after a single use. In addition, biodegradable foam peanuts do not have an electrostatic charge, meaning they will not stick to clothes.

Starch-based packing peanuts

In the early 1990s, starch-based packing peanuts were developed as a more environment-friendly alternative. The starch in the peanuts comes from crop-based sources rather than petroleum-based polystyrene, and is non-toxic. One of the first brands of biodegradable peanuts, Biofoam, is made from the grain sorghum;other brands are made from corn starch. Biodegradable foam peanuts have no electrostatic charge, another benefit over polystyrene. Being biodegradable and nontoxic, they are also safe for humans and pets if ingested accidentally.However, they are not produced in food-safe conditions, and are not recommended for eating. Also, during the manufacturing process, the nutritional value is removed from starch-based packing peanuts. This removes edible components, such as sugars, that would otherwise attract rodents and bugs. Their main drawbacks compared with polystyrene are lower resilience, higher weight (6.5 to 13 g per litre/0.4 to 0.8 lb per cubic foot), dust creation, potential attraction of rodents, and higher price. Starch-based peanuts are soluble in water, and polystyrene peanuts are soluble in acetone, but not vice versa.  Starch based products can be disposed with down the sink, dissolving on contact with the water.





https://greencellfoam.com/

https://www.superbiobag.com/biodegradable-foam/biodegradable-foam.html

This 'Nanowood' Is The Biodegradable Alternative To Styrofoam We Need

https://www.greenmatters.com/news/2018/03/14/Eafh8/nanowood-styrofoam
This is where a new material with the same convenience was developed at the University of Maryland. Nanowood is created from extra wood that’s mixed with cheap chemicals like sodium hydroxide and hydrogen peroxide. These chemicals take out the cell walls and leaves nanofibers of cellulose, or nanowood.

EcoCradle: Can mushroom packaging be the new wave for green purchasing?
http://www.earthtimes.org/going-green/ecocradle-biodegradable-mushroom-packaging/2112/

Biodegradable Styrofoam Made of Milk, Clay
https://www.seeker.com/biodegradable-styrofoam-made-of-milk-clay-discovery-news-1766491327.html
We already have plastics made from corn and sugar. Now, scientists have created a Styrofoam-like material using mostly milk proteins and clay.



Counter test

Blogger isn't letting me put my counter on the page.

 I can run it from an iframe.



But not directly...

And even odder is that all my gif are being and html over SSL is being replaced by my AT&T isp with webm and even putting the image as a base64 encoded data inline and not sent as a separate gif image.

I really am confused how this is they are doing some sort of man in the middle on my SSL sockets the could be end to end to my web server, that I control...


Thursday, July 9, 2020

State of the Art Supercapacitors, 3000uF 2.7v 3Wh



Maxwell Technologies  BCAP3000 P270 K05

1.124 lbs



https://www.mouser.com/ProductDetail/Maxwell-Technologies/BCAP3000-P270-K05?qs=TvYXSR6pz%2F1WUj0IwfQPeA%3D%3D


https://www.mouser.com/ProductDetail/PowerStor-Eaton/XL60-2R9348T-R?qs=f9yNj16SXrKO8xTIvD81mg%3D%3D

About $90 each.


To put this in perspective

Specific energy for:

    Diesel oil 
         12700 W·h/kg

    Lithium Ion Batteries 
   100–265 W·h/kg

    Supercaps
            5.7 W·h/kg




Tuesday, July 7, 2020

Tiny Weed-Killing Robots Could Make Pesticides Obsolete

Tiny Weed-Killing Robots Could Make Pesticides Obsolete
This swarm of robots may herald a chemical-free food revolution

https://onezero.medium.com/tiny-weed-killing-robots-could-make-pesticides-obsolete-99b3a6359c39


Clint Brauer’s farm outside of Cheney, Kansas, could be described as Old MacDonald’s Farm plus robots. Along with 5,500 square feet of vegetable-growing greenhouses, classes teaching local families to grow their food, a herd of 105 sheep, and Warren G—a banana-eating llama named after the rapper—is a fleet of ten, 140-pound, battery-operated robots.
Brauer, the co-founder of Greenfield Robotics, grew up a farm kid. He left for the big city tech and digital world, but eventually made his way back to the family farm. Now, it’s the R&D headquarters for the Greenfield Robotics team, plus a working farm.
When Brauer returned to his agricultural roots, he did so with a purpose: to prove that food could be grown without harmful chemicals and by embracing soil- and planet-friendly practices. He did just that, becoming one of the premier farmers growing vegetables in Kansas without pesticides, selling to local markets, grocery store chains, and chefs.
But it wasn’t enough to make the difference Brauer was hoping for. Sure, he was growing a lot of environmentally friendly, pesticide-free vegetables. But a few acres in chemical-free vegetable production was nothing compared to miles and miles of broadacre, arable farmland that make up the majority of America’s agricultural lands.
Brauer was especially intrigued by no-till solutions for soil health. No-till is exactly what it sounds like: farming without using techniques like plowing and cultivation, which “disturb” the soil to kill weeds. Many U.S. farmers, especially those in America’s heartland of corn, soy, and wheat production, have already switched to or are looking to embrace no-till practices. Over 104 million acres were farmed no-till in 2017, an increase of 8% since 2012. Just over 900 million acres, including no-till land, were farmed in the United States in 2017, according to the 2017 Census of Agriculture.
But parking machinery to improve soil health often comes with a trade that didn’t sit well with Brauer: dependence on chemical weed control. No-till works to improve soil health, but the trade-off in chemical use is not much better for the environment than conventional farming. Regardless of the type of farming, the problem is the same.
“You got to start with weeds. It’s the number one thing that farmers are fighting,” Brauer says.
That’s where the robots come in.
I’m a fourth-generation farmer. Easily half, if not more, of my time farming and certainly a huge portion of my expenses are spent on weed control. Right now, there are three basic solutions. None of them are perfect.
You can pull weeds out with good old human toil, an expensive and physically debilitating task. It’s increasingly hard to find help because frankly, hardly anybody wants to do it.
You can cultivate or “till” using mechanical solutions, like tractors pulling plows, discs, shovels, and rototillers that kill weed seedlings. But, as the no-till farmers have discovered, tillage disturbs the delicate microbial life of the soil, leading to decreasing yields, loss of topsoil, species diversity, and watershed destruction.
Then there’s door number three: herbicides. They are still expensive, but cheaper than labor. You can skip the tillage, but still control your weeds. Chemicals aren’t a perfect solution, but they have worked — sort of.
U.S. farmers choose the chemical option overwhelmingly often. According to the USDA, more than 95% of the U.S. corn and soybean crop was sprayed with herbicides in 2010 and 2012. A study published in the Environmental Health Journal last June showed that a whopping 1.2 billion pounds of pesticides were used in U.S. agriculture in 2016.
Glyphosate, aka “Roundup,” is the most commonly used herbicide in the world and the one most consumers have heard of. It was designated a probable human carcinogen by the World Health Organization’s cancer agency in 2015. The independent research group The Detox Project reports glyphosate may be an endocrine disruptor, and it’s unclear whether established “safe-use” levels are safe in the long term.
Overuse has led to glyphosate-resistant “superweeds.” In recent years, U.S. farmers have increasingly turned to less publicly known but potentially even more problematic chemical solutions, using pesticides that aren’t used in many other nations. Out of 25 of the most commonly used pesticides in U.S. agriculture, at least 10 are banned in one or more of the big three farm-producing regions of China, Brazil, and the European Union.
Dicamba is notorious for drifting and affecting nontarget crops miles away, yet manufacturers reported increasing sales until a June 4 ban in a U.S. appellate court. Atrazine is another popular herbicide. Found in 94% of all U.S. drinking watersheds, the Pesticide Action Network has raised concerns over its potential for endocrine disruption. Then there’s paraquat, a herbicide so deadly the CDC lists it on its “Chemical Emergency” website and it garners a fact sheet alongside arsenic, hydrogen cyanide, and mustard gas. Even though there’s currently a push to ban it internationally, paraquat has seen a recent resurgence in the U.S. as a solution to glyphosate-resistant weeds.
Keep in mind, farmers don’t use chemicals because they want to. Nobody understands better than farmers that the dependence on weed-killing chemicals is nothing but a sliding-scale deal with the devil. Not only do they pay for the chemicals, the labor and equipment to spray it, and (in some cases) the seeds that have been genetically modified so they can withstand them; farmers risk their own personal health every time they spray.
I have never met a farmer who looked forward to mixing tanks of hazardous chemicals and sitting on their butt on a tractor spraying for days on end. There are plenty of more fulfilling tasks to do on a farm.
But those dang weeds.
The Greenfield robotic solution is based on a simple idea: Keep mowing.
When Brauer started thinking about which weed to target first, pigweed was an obvious first enemy. The pain-in-the-ass weed, also known as Palmer amaranth, claims the annoying weed holy grail — it is invasive, adaptive, and herbicide-resistant. A single plant, undeterred, can grow over six feet tall and produce up to half a million tiny seeds. It distributes easily, and young seedlings continue to germinate even after the cash crop is planted. Farmers have to keep working to get rid of it even after their crop starts growing, otherwise, it quickly takes over. Because it has become glyphosate-resistant, desperate farmers have increasingly turned to more aggressive chemical solutions.
Image for post
A Greenfield Robotics ‘broadleaf weedbot’ gets busy.
On a whim, Brauer threw a mower on his tractor and took it to a field that had been overtaken by the weed. He discovered that if mowed repeatedly, a few inches off the ground, the pigweed would eventually give up the fight and die.
But when you mow down a field of pigweed, you’re mowing everything down. Including, technically, the crop you’re trying to grow. A standard-size tractor and mower won’t fit between rows of soy, corn, cotton, or any other broadacre crop, which are typically seeded in rows 30 inches apart. And a heavy tractor and mower can’t go into fields when it’s too wet, or they risk the catastrophe called “planting your tractor” — otherwise known as getting stuck.
Plus, staying in front of pigweed’s lightning-fast growth rate would require an almost nonstop mowing regime.
So, Brauer turned to robots. Autonomous mowing machines were small enough to fit between rows, light enough to work in muddy fields, and, the best part — they could do it by themselves. Better yet, a whole fleet of them could.
Brauer reached out to an old friend, Steven Gentner, founder of RoboRealm, a machine vision software company. Unlike most industries looking for “machine visioning” solutions, teaching robots to see crop rows would be relatively easy.
“His exact words, ‘I get pitched stupid ideas all the time that aren’t going to work for a long time. This one is doable,’” Brauer says.
Gentner started out his career with a degree in robotics and was temporarily distracted by the dot-com explosion, where he met Brauer. Eventually, he switched back into robotics. Now, he gets positively giddy talking about the combo of robotics and farming, especially as it applies to Big Ag.
Large-scale agricultural production is already well suited for robots because it is so hyper-controlled. Large-acreage farmers plant straight rows that go on for miles of exactly the same thing, exactly the same distance apart.
“Agriculture right now is just booming in terms of robotics. It makes so much sense,” Gentner says.
To envision Brauer’s idea, Gentner started first with a remote-controlled mower, the operator walking behind it like a toy race-car driver. The second-generation model added the machine vision feature and moved the operator out of the field.
This summer, they added the final “full automatic with onboard computing” component combined with out-of-the-field computer monitoring.
Each “broadleaf weeding bot” has a sensor that allows it to sense depth. It can “see” the planted rows in the field that stretch into the distance through machine vision. Gentner combined that capability with standardized row spacing data, then overlaid the whole thing with a real-time kinematic GPS map. There is still an operator onsite, but sitting out of the field. They monitor the robots remotely in the case of an unforeseen incident the robots can’t traverse (like a bit of netting wrapped up in the mowing blades).
The robots see and follow the “depth” of the rows, know how much space should be between each row, and follow a preprogrammed precision map if anything goes awry. Whatever is in front of them? They mow it.
Across the Atlantic in the British Islands, farmers have similar weed problems but even fewer chemical control options, making robotics even more attractive.
Many of the herbicides popular in the United States, including atrazine and paraquat, have been banned in the U.K. because of a European Union crackdown on chemicals deemed to be of human health and environmental concerns. Even glyphosate is under close scrutiny. U.K. farmers believe it will soon be restricted as well, leaving them even more desperate for a nonchemical solution, says Suffolk County farmer Tom Jewers, a member of a farmer’s advisory board for the Small Robot Company.
Not that the type of herbicide you use matters when it comes to fighting the bane of Jewers’ existence — black grass, or Alopecurus myosuroides. At least in Jewers’ experience.
Black grass, like pigweed, is a highly adaptable weed that seems to circumvent all control methods except for hand-weeding. It has taken root in U.K. farmlands due to years of intensive tillage that compacted the soil, creating ideal conditions for the weed to take root. Jewers believes that if he can transition to no-till farming practices, his soil will improve enough to naturally reduce his black-grass infestation. But to do so, he still has to control the black grass in the years it will take for the soil to improve. It’s a chicken-and-egg problem with no good solutions. Except robots.
“I have the entire family out in a field today, pulling black grass out by hand because we haven’t got a robot yet, and we can’t control it chemically,” Jewers said.
Image for post
The Small Robot Company tech team with the weed mapping robot Tom during its first outing. Photo: Small Robot Company
The Small Robot Company is a UK-based agricultural robotic startup that makes robots that electrically “zap” weed seedlings. It finalized a €2.1 million ($2.4 million) crowd-equity funding round, bringing its venture capital fund-raising up to €5 million to date.
Founded in 2015 with a four-robot crew — Tom, Dick, Harry, and Wilma — it initially focused on robotic field mapping and planting solutions. But it quickly got the same message from farmers that Greenfield heard: weeds, please.
The Small Robot Company differentiates between weeds and crops differently than Greenfield. Instead of relying on established rows of crops for the robots to see and follow, it focused instead on highly advanced “better than the eye can see” scanning and photographic technology.
Tom starts off the process by rolling through the field and mapping it. That information is uploaded to Wilma. Then Wilma tells “Dick,” the weed zapper, to get to work, explains Sarra Mander, CMO of the Small Robot Company.
Image for post
Small Robot Company’s weed-zapping robot “Dick.” Photo: Small Robot Company
Dick, which is about the size of a small car, follows Wilma’s directions and moves through the field at a walking pace, identifying each weed seedling based on the prior mapping data. Then, it sends a mini “lightning strike” through each weed seedling, leaving the cash crop seedlings unzapped.
“The point isn’t speed; it’s accuracy,” Mander says. This solution is more complicated than Greenfields mowers, but it allows for weed control in crops that are planted much more closely together. The Small Robot Company will be going into field trials with its weed-zapping “Dick” robot this fall.
In its early trials back in Kansas, the Greenfield team ran into some unforeseen obstacles: A shovel. Netting. A gopher hole. When that happens, the robot turns off the mower, then the off-site operator backs it out and navigates the problem remotely. But nature sometimes has different ideas.
A robot got stuck in a no-till field filled with debris and sticks and attempted to back out and try again, but a stick torqued at just the right angle to hit the power button, turning it off in the middle of the field.
“In a million years you could never get that work if you tried, but it just randomly happens,” says Gentner. “Nature has a fascinating way of teaching you how to be humble and to respect it.”
Now solidly into year three, Greenfield has learned from those mistakes. It has currently signed up several farms for the 2020 growing season for “beta test” field trials. With Brauer’s background in farming and close familiarity with tight agricultural budgets, the company priced the trials to cost no more than a farms’ current chemical annual weed control expenses, roughly $30 an acre. Instead of paying for a chemical weed control solution (typically around $25 to $60 an acre), farmers contract with the Greenfield robotic fleet to accomplish the same objective, at no additional cost, sans chemicals.
The company has raised $500,000 in an angel investment round and will start a push for $8 million in additional funding this fall, but doing so has required educating investors about how revolutionary a robotic weed solution could be. Educating them has been an interesting challenge, says Nandan Kalle, a Greenfield team member.
“How do you explain the benefits of ‘no-till’ to someone who doesn’t know what ‘till’ means?” Kalle asks. But people can learn: Not so long ago Kalle too was a farming newbie who was called in for a company emergency: The sheep were out — again.
“I think we are the only tech startup that has to worry about chasing runaway sheep at night,” Kalle says.
Greenfield is working on a second-generation model that offers a similar level of precision as the Small Robot Company but uses a different technology. Gentner doesn’t seem to mind the competition: There are so many potential applications for robotics in agriculture, he says, that there’s plenty of room for competition. There’s certainly no dearth of weeds.
As a farmer, I have both a highly attuned sense of skepticism for the latest new “solution” that will “save” my farm. Yet, like all farmers, I am constantly evaluating ways to do it better. Should I purchase a new tool or piece of equipment? Try that new organic pesticide or herbicide my neighbors had luck with? Or do I simply need to rethink my way of doing the work?
Certainly, farmers aren’t opposed to new tech or new ideas. We all know that’s the name of the game; we just need them to work in the real world of food production. And not cost a gazillion dollars. Successful farming is a constant process of tweaking and adjusting, adapting to a new problem, or finding the solution to fix an old headache. Like weeds.
Even if robots end up doing nothing else for farmers but just controlling weeds, that alone has the potential to revolutionize agriculture.
If I was a Big Ag chemical company, I’d be worried. The farm bots are coming.


Editor’s note: While it’s generally true that pesticides are used to kill pests and herbicides are used to kill weeds, the U.S. Environmental Protection Agency defines both agents for killing pests and weeds as “pesticides.” By the government’s definition, pests can be both bugs and weeds.